Secondary Colors:

Red and yellow always make some kind of orange, yellow and blue a green, and blue and red a purple. The actual color you get depends on which primary you're using and the proportions in which you mix the two primaries. Paint a color chart where you record which two colors you mixed and the (approximate) proportions of each. This will provide you with a ready reference until you get to the stage when you instinctively know what you'll get.
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